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Application of solid-phase microextraction combined with
gas chromatography-mass spectrometry to the determination
of butylated hydroxytoluene in bottled drinking water.

J Chromatogr A 2002 Jul 19;963(1-2):179-83 Jul02

Tombesi NB, Freije H.

Quimica Ambiental, Departamento de Quimica e Ingenieria Quimica, Universidad Nacional del Sur, Bahia Blanca, Argentina. ustombes@criba.edu.ar

Butylated hydroxytoluene (BHT) is an antioxidant utilized as additive in foods and packaging plastic. Its presence in drinking water is possible if it is used as an antioxidant in the packaging plastic because it may migrate into the package's contents. A method for the determination of BHT in water by means of solid-phase microextraction and gas chromatography-mass spectrometry has been developed and evaluated with respect to the time of fiber exposure, limits of detection and quantitation, linearity and precision. Finally, the method was applied to evaluate the presence of this substance in samples of mineral and mineralized bottled drinking water, and it appeared to be present in seven out of a total of fifteen commercial brands.

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