Roundup Brush Killer Concentrate MSDS #7020
MATERIAL SAFETY DATA SHEET
DATE PREPARED: 04/07/1999
MSDS No: 7020
1. PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT NAME: Roundup® Brush Killer Concentrate
PRODUCT DESCRIPTION: Herbicide
MANUFACTURERMonsanto CompanyLawn & Garden Products P.O. Box 1750 Columbus, OH 43216 |
24 HR. EMERGENCY TELEPHONE NUMBERSEmergency Phone: 1-800-225-2883 |
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EPA REG. NO.: 71995-20 PN: 6056A
2. COMPOSITION / INFORMATION ON INGREDIENTS
| Chemical Name | Wt.% | CAS# | ||
|---|---|---|---|---|
| Glyphosate, isopropylamine salt | 38641-94-0 | |||
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
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PHYSICAL APPEARANCE: Clear light amber liquid
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IMMEDIATE CONCERNS: CAUSES EYE IRRITATION
AVOID CONTACT WITH EYES OR CLOTHING
WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING
KEEP OUT OF REACH OF CHILDREN
POTENTIAL HEALTH EFFECTS
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EYES: Eye contact may cause discomfort, tearing,
swelling, redness, and blurred vision. See Toxicology Information,
section 11.
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SKIN: This substance is not expected to cause
prolonged or significant skin irritation. If absorbed through the
skin, this substance is considered practically non-toxic to internal
organs. This product is not expected to cause allergic skin reaction.
See Toxicology Information, section 11.
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INGESTION: Ingestion may produce irritation of
the digestive tract as demonstrated by signs and symptoms of mouth
membrane irritation, nausea, vomiting and diarrhea. See Toxicology
Information, section 11.
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INHALATION: Overexposure to spray mist may
result in minor irritation of the upper respiratory tract. See
Toxicology Information, section 11.
4. FIRST AID MEASURES
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EYES: If in eyes, immediately flush with
plenty of water. Get medical attention if irritation persists.
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SKIN: No first aid procedures are
required. Wash skin thoroughly with soap and water after handling.
Remove and wash contaminated clothing.
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INGESTION: If swallowed, immediately
telephone a poison control center, emergency treatment center or a
physician for advice. DO NOT make person vomit unless directed to do
so by medical personnel. If medical advice cannot be obtained, then
immediately take person and product container, with label, to an
emergency treatment center.
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INHALATION: If respiratory discomfort or
irritation occurs, move the person to fresh air. See a doctor if
discomfort or irritation continues.
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ADDITIONAL INFORMATION: Medical
Information: Call day or night, 1-800-225-2883
5. FIRE FIGHTING MEASURES
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FLASHPOINT AND METHOD: >200°F TAG CC
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EXTINGUISHING MEDIA: Water spray, foam,
CO2, dry chemical or any class B extinguishing agent.
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HAZARDOUS COMBUSTION PRODUCTS: This
material will not burn.
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FIRE FIGHTING PROCEDURES: For fires
involving this material, do not enter any enclosed or confined fire
space without proper protective equipment. This may include
self-contained breathing apparatus to protect against the hazardous
effects of normal products of combustion or oxygen deficiency. Read
the entire document.
6. ACCIDENTAL RELEASE MEASURES
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SMALL SPILL: Soak up spilled material
with paper towels and discard in trash.
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LARGE SPILL: Liquid spills on floor or
other impervious surfaces should be contained or diked, and should be
absorbed with attapulgite, bentonite or other absorbent clays. Collect
contaminated absorbent, place in plastic-lined metal drum and dispose
of in accordance with instructions provided under Section 13.
"DISPOSAL". Thoroughly scrub floor or other impervious
surface with a strong industrial type detergent solution and rinse
with water.
For liquid spills that soak into the ground, contact the applicable Federal, State and or County Health Dept. for disposal recommendations. If disposal is required then refer to Section 13 "DISPOSAL" for instructions.
Leaking containers should be separated from non-leakers and either the container or its contents transferred to a drum or other non-leaking container and disposed of in accordance with instructions provided under Section 13 "Disposal". Any recovered spilled liquid should be similarly collected and disposed of.
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GENERAL PROCEDURES: Observe all
protection and safety precautions when cleaning up spills -- see
Section 8. "EXPOSURE CONTROLS/PERSONAL PROTECTION". For help
with any spill, leak, fire or exposure involving this material, call
day or night (800) 225-2883.
7. HANDLING AND STORAGE
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GENERAL PROCEDURES: Store this product
only in its original container in a secured storage area. Protect
container from freezing.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
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ENGINEERING CONTROLS: No special ventilation
is necessary.
PERSONAL PROTECTION
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EYES AND FACE: Workers handling the concentrate
should wear chemical goggles to prevent eye contact during
mixing/transfer operations or other activities where there is
potential for eye contact with the concentrated product. The wearing
of goggles is not required during use of this product in accordance
with label instruction.
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SKIN: Although this product does not present a
significant skin concern, minimize skin contamination by following
good industrial practice. Wearing protective gloves is recommended.
Wash hands and contaminated skin throughly after handling.
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RESPIRATORY: For Handling the Concentrated
Product: Avoid breathing vapor or mist. This product concentrate is
not likely to pose an airborne exposure concern during manufacture or
packaging. In the event of abnormal exposure conditions, use
NIOSH/MSHA approved equipment. In work situations where an air
purifying respirator is appropriate to be used, use of a full face
respirator equipped with purifying elements for protection against
organic vapor and dust/mist approved for pesticides is recommended.
Use Cartridges with NIOSH/MSHA approval number TC-23C or canister with
NIOSH/MSHA approval number TC-14G. Full facepiece replaces the need
for chemical goggles. Observe respirator use limitations specified by
the manufacturers. Respiratory protection programs must comply with 29
CFR 1910.134.
For Use of Product in accordance with label instructions: Respirators are not required for use of this product in accordance with label instructions.
9. PHYSICAL AND CHEMICAL PROPERTIES
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PHYSICAL STATE: Liquid
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ODOR: Practically odorless to slight
amine-like odor
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COLOR: Clear amber to yellow liquid
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pH: ~4.6 to 5.0
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SOLUBILITY IN WATER: Soluble
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DENSITY: 9.24 lb/gal
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VISCOSITY: No Data Available
10. STABILITY AND REACTIVITY
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STABLE: YES
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HAZARDOUS POLYMERIZATION: NO
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STABILITY: Product is stable for at least
5 years under normal conditions of warehouse storage.
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INCOMPATIBLE MATERIALS: Do not apply with
a galvanized or unlined steel sprayer, or through any irrigation
system.
11. TOXICOLOGICAL INFORMATION
ACUTE
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EYES: Moderately irritating to rabbit eyes;
irritation cleared by test day 7 (EPA FIFRA Toxicity Category - lll).
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DERMAL LD50:
Rat = > 5.0 g/kg. EPA FIFRA toxicity category - IV.
SKIN IRRITATION: Rabbit - slightly irritating. EPA FIFRA toxicity category - IV.
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ORAL LD50: Rat
= >5.0 g/kg.
EPA FIFRA toxicity category - IV.
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INHALATION LC50:
Found to be practically nontoxic to rats following a 4-hour inhalation
exposure; the inhalation LC50 is >3.3 mg/L (EPA FIFRA Toxicity
Category - IV).
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SENSITIZATION: Guinea pig - no evidence
of allergic skin reactions.
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CHRONIC: Data from glyphosate laboratory
toxicology studies were conducted with a formulation comprised of 62%
isopropylamine salt of glyphosate (MON 0139).
Rabbits - 3 week dermal: Repeated daily primarily resulted in slight skin irritation.
Dogs - 6 month feeding: Only slight body weight changes noted.
Rats - 90 day feeding: No treatment related effects.
Mice - 90 day feeding: Decreased weight gains at the high dose level group animals.
CARCINOGENICITY:
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CARCINOGENICITY COMMENTS: GLYPHOSATE:
Glyphosate is not considered to be a carcinogen. Glyphosate did not
produce tumors in any of the long-term toxicology studies. EPA has
classified glyphosate in category "E" (Evidence of
noncarcinogenicity for humans).
Mice: 2-year feeding study. Reduced body weight gain and effects on liver tissues were observed at high dose levels.
Rats: 2-year feeding study. Reduced body weight gain and eye changes were observed at the high dose level in one study, while no treatment related effects occurred in a second study conducted at lower dose levels.
Dogs: No adverse effects were observed in feeding studies with dogs.
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NEUROTOXICITY: GLYPHOSATE: There was no
evidence of nervous system toxicity, including delayed induced
peripheral neuropathy in chickens (repeated oral dosing) or
cholinesterase inhibition in rats (single oral dosing).
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TERATOGENICITY: GLYPHOSATE: No evidence
of teratogenic effects. Results of rat and rabbit teratology studies
indicate that no birth defects were noted. This included dose levels
of glyphosate that were maternally toxic.
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REPRODUCTIVE TOXIN: GLYPHOSATE: No
evidence of adverse reproductive effects. Glyphosate was fed
continuously to rats at very high dose levels for 2 successive
generations. Toxicity was reported in offspring from the high dose, a
level which also produced adverse effects on the mothers. In a
3-generation study conducted at lower dose levels, no effects were
seen on the ability of male or female rats to reproduce.
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MUTAGENICITY: GLYPHOSATE: Glyphosate has
not produced any genetic changes in various mutagenicity tests
involving animals and animal or bacterial cells.
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COMMENTS: See Section 16 for definition of EPA
FIFRA toxicity categories.
12. ECOLOGICAL INFORMATION
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ENVIRONMENTAL DATA: Do not apply directly
to water. Do not contaminate water when disposing of equipment
washwaters.
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ECOTOXICOLOGICAL INFORMATION: Studies
performed with a concentrated solution of the isopropylamine salt of
glyphosate indicate the following:
MON 0139 Technical (62%)
48-hr LC50 Daphnia: 930 mg/L, Practically Nontoxic
96-hr LC50 Bluegill: >1,000 mg/L, Practically Nontoxic
96-hr LC50 Trout: >1,000 mg/L, Practically Nontoxic
96-hr LC50 Carp: >10,000 ppm, Practically Nontoxic
13. DISPOSAL CONSIDERATIONS
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FOR LARGE SPILLS: Material collected that
cannot be reprocessed should be disposed of in a landfill approved for
pesticide disposal or in accordance with applicable Federal, State or
local procedures.
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PRODUCT DISPOSAL: Securely wrap partially
filled or empty container in several layers of newspaper and discard
in trash.
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EMPTY CONTAINER: Do not reuse container.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
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PROPER SHIPPING NAME: Not Regulated
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PRIMARY HAZARD CLASS/DIVISION: None
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UN/NA NUMBER: None
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PACKING GROUP: No
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U.S. SURFACE FREIGHT CLASS: Tree or weed
killing compounds, NOI, Density of 20 lbs. or greater per cu. ft.
AIR (ICAO/IATA)
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PROPER SHIPPING NAME: Not Regulated
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SPECIAL SHIPPING NOTES: The description
shown may not apply to all shipping situations. Consult 49CFR, or
appropriate Dangerous Goods Regulations, for additional description
requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
| PRODUCT CLASSIFICATION UNDER SECTION 311 OF SARA | ||||
| ACUTE: YES | CHRONIC: NO | FIRE: NO | REACTIVITY: NO | PRESSURE GENERATING: NO |
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311/312 HAZARD CATEGORIES: Immediate
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313 REPORTABLE INGREDIENTS: None
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TITLE III NOTES: Immediate (acute) health
hazard: Product is moderately irritating to the eyes.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
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TSCA REGULATORY: All non FIFRA regulated
components are on the US EPA's TSCA Inventory List.
STATE REGULATIONS
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PROPOSITION 65 STATEMENT: No ingredients
on list.
16. OTHER INFORMATION
HMIS CODES
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FIRE: 0 HEALTH: 1 REACTIVITY: 0 PROTECTION:
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NFPA CODES
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FIRE: 0 HEALTH: 1 REACTIVITY: 0 SPECIAL: -
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APPROVAL DATE: 11/03/2000
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REVISION SUMMARY Revision #: 1
This MSDS replaces the April 13, 1999 MSDS. Any changes in information are as follows:
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MANUFACTURER SUPPLEMENTAL NOTES: EPA
FIFRA (Federal Insecticide, Fungicide and Rodenticide Act) Toxicity
Categories: The EPA toxicity categories are based on the results of
the acute toxicology studies. The toxicology findings are compared to
the FIFRA criteria to determine the product label signal word,
precautionary and first aid statements. The EPA FIFRA toxicity
category summary:
EPA FIFRA Product Label Toxicity Rating
Toxicity Category Signal Word
I DANGER Most toxic and irritating
II WARNING
III CAUTION
IV CAUTION Least toxic and irritating
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COMMENTS: For additional information
concerning this product, call the Helpline at 800-225-2883.
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MANUFACTURER DISCLAIMER: This Material
Safety Data Sheet (MSDS) contains health, safety and environmental
information for you and your employees. It does not replace the
precautionary language, use directions, or the storage and disposal
information found on the product label. Information contained in this
MSDS will help you to prepare for emergency response and to meet
community right-to-know, emergency response and reporting requirements
under SARA Title III and many other laws. Emergency response agencies
and health care providers will also find this additional information
useful.
Use of this product is regulated by the U.S. Environmental Protection Agency (EPA) through the approved label copy. It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
Although the information and recommendations set forth herein (herinafter "Information") are presented in good faith and believed to be correct as of the date hereof, Monsanto Company makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determinations as to its suitability for their purposes prior to use. In no event will Monsanto Company be responsible for damages of any nature whatsoever resulting from the use of or reliance upon Information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS.
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