Roundup Sure Shot Foam MSDS # 7016
MATERIAL SAFETY DATA SHEET
DATE PREPARED: 04/07/1999
MSDS No: 7016
1. PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT NAME: Roundup Sure Shot Foam
PRODUCT DESCRIPTION: Herbicide
MANUFACTURERMonsanto CompanyLawn & Garden Products P.O. Box 1750 Columbus, OH 43216 |
24 HR. EMERGENCY TELEPHONE NUMBERSEmergency Phone: 1-800-225-2883 |
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EPA REG. NO.: 71995-16 PN: 100-116A
2. COMPOSITION / INFORMATION ON INGREDIENTS
| Chemical Name | Wt.% | CAS# | ||
|---|---|---|---|---|
| Glyphosate, isopropylamine salt | 38641-94-0 | |||
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
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PHYSICAL APPEARANCE: White, creamy smooth liquid
in aerosol container
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IMMEDIATE CONCERNS: CAUSES EYE IRRITATION
AVOID CONTACT WITH EYES OR CLOTHING
WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING
KEEP OUT OF REACH OF CHILDREN
POTENTIAL HEALTH EFFECTS
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EYES: This substance causes moderate eye
irritation as indicated by possible discomfort, tearing, swelling,
redness, and blurred vision. See Toxicological Information, section
11.
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SKIN: This substance is not expected to cause
skin irritation. See Toxicological Information, section 11.
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INGESTION: If swallowed, this product may cause
gastrointestinal tract irritation. See Toxicological Information,
section 11.
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INHALATION: If inhaled, this substance is
considered practically non-toxic to internal organs. This substance
may be irritating if inhaled. See Toxicological Information, section
11.
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COMMENTS HEALTH: Inhalation and skin
contact are expected to be the primary routes of occupational exposure
to ROUNDUP Sure Shot Foam. Occupational exposure to this material has
not been reported to cause significant adverse health effects.
However, swallowing of a similar, but more concentrated formulation,
has been reported to produce gastrointestinal discomfort, nausea,
vomiting and diarrhea.
4. FIRST AID MEASURES
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EYES: Flush eyes immediately with fresh
water for at least 15 minutes while holding the eyelids open. Remove
contact lenses if worn. Call a physician if irritation persists.
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SKIN: No first aid procedures are
required. As a precaution, wash skin thoroughly with soap and water.
Remove and wash contaminated clothing.
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INGESTION: If swallowed, immediately
telephone a poison control center, emergency treatment center or a
physician for advice. DO NOT make person vomit unless directed to do
so by medical personnel. If medical advice cannot be obtained, then
immediately take person and product container, with label, to an
emergency treatment center.
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INHALATION: Since this material is not
expected to be an immediate inhalation problem, no first aid
procedures are required. If respiratory discomfort or irritation
occurs, move the person to fresh air. See a doctor if discomfort or
irritation continues.
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ADDITIONAL INFORMATION: In case of
medical emergencies involving this product, call day or night,
1-800-225-2883.
5. FIRE FIGHTING MEASURES
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FLASHPOINT AND METHOD: >200°F TAG CC
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EXTINGUISHING MEDIA: Water spray, foam,
CO2, dry chemical or any class B extinguishing agent.
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FIRE FIGHTING PROCEDURES: For fires
involving this material, do not enter any enclosed or confined fire
space without proper protective equipment. This may include
self-contained breathing apparatus to protect against the hazardous
effects of normal products of combustion or oxygen deficiency. Keep
containers cool with a water spray. Read the entire document.
6. ACCIDENTAL RELEASE MEASURES
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SMALL SPILL: Soak up spilled material
with paper towels and discard in trash.
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LARGE SPILL: Liquid spills on floor or
other impervious surfaces should be contained or diked, and should be
absorbed with attapulgite, bentonite or other absorbent clays. Collect
contaminated absorbent, place in plastic-lined metal drum and dispose
of in accordance with instructions provided under Section 13.
"DISPOSAL". Thoroughly scrub floor or other impervious
surface with a strong industrial type detergent solution and rinse
with water.
For liquid spills that soak into the ground, contact the applicable Federal, State and or County Health Dept. for disposal recommendations. If disposal is required then refer to Section 13 "DISPOSAL" for instructions.
Leaking containers should be separated from non-leakers and either the container or its contents transferred to a drum or other non-leaking container and disposed of in accordance with instructions provided under Section 13 "Disposal". Any recovered spilled liquid should be similarly collected and disposed of.
Do not contaminate water, foodstuffs or feed by storage or disposal.
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GENERAL PROCEDURES: Observe all
protection and safety precautions when cleaning up spills -- see
Section 8. "EXPOSURE CONTROLS/PERSONAL PROTECTION". For help
with any spill, leak, fire or exposure involving this material, call
day or night (800) 225-2883.
7. HANDLING AND STORAGE
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GENERAL PROCEDURES: READ AND OBSERVE ALL
PRECAUTIONS ON PRODUCT LABEL. Store in accordance with NFPA 30B for a
Level I aerosol. DO NOT USE OR STORE near flame, sparks or hot
surfaces. USE ONLY IN WELL VENTILATED AREA. CONTAINER UNDER PRESSURE.
Exposure to heat or prolonged exposure to sun may cause container to
burst. Do not puncture, incinerate or store above 130°F.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
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ENGINEERING CONTROLS: No special ventilation
is necessary.
PERSONAL PROTECTION
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EYES AND FACE: For application of product in
accordance with label instructions, no special eye protection is
needed.
Where there is significant potential for eye contact, wear chemical goggles and have eye flushing equipment available.
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SKIN: Although this product does not present a
significant skin concern, minimize skin contamination by following
good industrial practice. Wearing protective gloves is recommended.
Wash hands and contaminated skin throughly after handling.
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RESPIRATORY: Avoid breathing vapor or mist. Use
NIOSH/MSHA approved respiratory protection equipment when airborne
exposure limits are exceeded (see below). Consult respirator
manufacturer to determine appropriate type equipment for given
application. Observe respirator use limitations specified by
NIOSH/MSHA or the manufacturer. Respiratory protection programs must
comply with 29 C.F.R. 1910.134.
For application of product in accordance with label instructions, no special respiratory protection is required.
9. PHYSICAL AND CHEMICAL PROPERTIES
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PHYSICAL STATE: Aerosol
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APPEARANCE: Creamy, white liquid in
aerosol canister
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pH: ~6.7 to 7.1
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SOLUBILITY IN WATER: Soluble
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DENSITY: 8.43 lbs./gal. at 20°C
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SPECIFIC GRAVITY: 1.0124 gr/cc
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VISCOSITY: Same as water.
10. STABILITY AND REACTIVITY
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STABLE: YES
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HAZARDOUS POLYMERIZATION: YES
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HAZARDOUS DECOMPOSITION: None.
11. TOXICOLOGICAL INFORMATION
ACUTE
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EYES: Rabbit - moderately irritating, irritation
cleared by test day 7.
EPA FIFRA toxicity category - III.
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DERMAL LD50:
The hazard evaluation for this product was based on the non-aerosol
form of the product. Pratically non-toxic, (Rat LD50 >5000 mg/Kg).
Non irritating to skin (Rabbits). EPA FIFRA toxicity category - IV.
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ORAL LD50: The
hazard evaluation for this product was based on the non-aerosol form
of the product. Practically non-toxic, (Rat LD50 >5000 mg/Kg). EPA
FIFRA toxicity category - IV.
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INHALATION LC50:
The hazard evaluation for this product was based on the non-aerosol
form of the product. Practically non-toxic, (Rat 4-hr LC50
>10mg/L). EPA FIFRA toxicity category - IV.
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SENSITIZATION: Guinea pig - no evidence
of allergic skin reactions.
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SUBCHRONIC: Data from glyphosate
laboratory toxicology studies were conducted with a formulation
comprised of 62% isopropylamine salt of glyphosate (MON 0139).
Rabbits - 3 week dermal: Repeated daily primarily resulted in slight skin irritation.
Dogs - 6 month feeding: Only slight body weight changes noted.
Additional toxicity information is available on glyphosate, the
active herbicidal ingredient of MON 0139.
Rats - 90 day feeding: No treatment related effects.
Mice - 90 day feeding: Decreased weight gains at the high dose level
group animals.
CARCINOGENICITY:
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CARCINOGENICITY COMMENTS: GLYPHOSATE:
Glyphosate is not considered to be a carcinogen. Glyphosate did not
produce tumors in any of the long-term toxicology studies. EPA has
classified glyphosate in category "E" (Evidence of
noncarcinogenicity for humans).
Mice: 2-year feeding study. Reduced body weight gain and effects on liver tissues were observed at high dose levels.
Rats: 2-year feeding study. Reduced body weight gain and eye changes were observed at the high dose level in one study, while no treatment related effects occurred in a second study conducted at lower dose levels.
Dogs: No adverse effects were observed in feeding studies with dogs.
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TERATOGENICITY: GLYPHOSATE: No evidence
of teratogenic effects. Results of rat and rabbit teratology studies
indicate that no birth defects were noted. This included dose levels
of glyphosate that were maternally toxic.
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REPRODUCTIVE TOXIN: GLYPHOSATE: No
evidence of adverse reproductive effects. Glyphosate was fed
continuously to rats at very high dose levels for 2 successive
generations. Toxicity was reported in offspring from the high dose, a
level which also produced adverse effects on the mothers. In a
3-generation study conducted at lower dose levels, no effects were
seen on the ability of male or female rats to reproduce.
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MUTAGENICITY: GLYPHOSATE: Glyphosate has
not produced any genetic changes in various mutagenicity tests
involving in vivo animals or in vitro cellular studies.
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COMMENTS: See Section 16 for definition of EPA
FIFRA toxicity categories.
12. ECOLOGICAL INFORMATION
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ECOTOXICOLOGICAL INFORMATION: Studies
performed with a concentrated solution of the isopropylamine salt of
glyphosate indicate the following:
MON 0139 Technical (62%)
48-hr LC50 Daphnia: 930 mg/L, Practically Nontoxic
96-hr LC50 Bluegill: >1,000 mg/L, Practically Nontoxic
96-hr LC50 Trout: >1,000 mg/L, Practically Nontoxic
96-hr LC50 Carp: >10,000 ppm, Practically Nontoxic
13. DISPOSAL CONSIDERATIONS
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FOR LARGE SPILLS: Material collected that
cannot be reprocessed should be disposed of in a landfill approved for
pesticide disposal or in accordance with applicable Federal, State or
local procedures.
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PRODUCT DISPOSAL: Securely wrap partially
filled or empty container in several layers of newspaper and discard
in trash.
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EMPTY CONTAINER: If recycling is not
available, replace cap, wrap container and discard in trash.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
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PROPER SHIPPING NAME: Consumer Commodity
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PRIMARY HAZARD CLASS/DIVISION: ORM-D
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UN/NA NUMBER: None
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PACKING GROUP: No
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U.S. SURFACE FREIGHT CLASS: NMFC NBR.
102120
AIR (ICAO/IATA)
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PROPER SHIPPING NAME: Consumer Commodity
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SPECIAL SHIPPING NOTES: The description
shown may not apply to all shipping situations. Consult 49CFR, or
appropriate Dangerous Goods Regulations, for additional description
requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
| PRODUCT CLASSIFICATION UNDER SECTION 311 OF SARA | ||||
| ACUTE: NO | CHRONIC: NO | FIRE: NO | REACTIVITY: NO | PRESSURE GENERATING: NO |
TSCA (TOXIC SUBSTANCE CONTROL ACT)
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TSCA REGULATORY: All non FIFRA regulated
components are on the US EPA's TSCA Inventory List.
STATE REGULATIONS
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PROPOSITION 65 STATEMENT: No ingredients
on list.
16. OTHER INFORMATION
HMIS CODES
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FIRE: 0 HEALTH: 1 REACTIVITY: 0 PROTECTION:
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NFPA CODES
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FIRE: 0 HEALTH: 1 REACTIVITY: 0 SPECIAL: -
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APPROVAL DATE: 11/03/2000
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REVISION SUMMARY Revision #: 1
This MSDS replaces the April 13, 1999 MSDS. Any changes in information are as follows:
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MANUFACTURER SUPPLEMENTAL NOTES: EPA
FIFRA (Federal Insecticide, Fungicide and Rodenticide Act) Toxicity
Categories: The EPA toxicity categories are based on the results of
the acute toxicology studies. The toxicology findings are compared to
the FIFRA criteria to determine the product label signal word,
precautionary and first aid statements. The EPA FIFRA toxicity
category summary:
EPA FIFRA Product Label Toxicity Rating
Toxicity Category Signal Word
I DANGER Most toxic and irritating
II WARNING
III CAUTION
IV CAUTION Least toxic and irritating
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COMMENTS: For additional information
concerning this product, call the Helpline at 800-225-2883.
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MANUFACTURER DISCLAIMER: This Material
Safety Data Sheet (MSDS) contains health, safety and environmental
information for you and your employees. It does not replace the
precautionary language, use directions, or the storage and disposal
information found on the product label. Information contained in this
MSDS will help you to prepare for emergency response and to meet
community right-to-know, emergency response and reporting requirements
under SARA Title III and many other laws. Emergency response agencies
and health care providers will also find this additional information
useful.
Use of this product is regulated by the U.S. Environmental Protection Agency (EPA) through the approved label copy. It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
Although the information and recommendations set forth herein (herinafter "Information") are presented in good faith and believed to be correct as of the date hereof, Monsanto Company makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determinations as to its suitability for their purposes prior to use. In no event will Monsanto Company be responsible for damages of any nature whatsoever resulting from the use of or reliance upon Information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS.
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